Suitable explanation for the order of basic character, $(C H_{3})_{3} N < (C H_{3})_{2} N H$ , is:

steric hindrance by bulky methyl group

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higher volatility of

3^{\circ}

amine

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stability of conjugate acid due to solvation

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all of these

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Solution

The correct option is A steric hindrance by bulky methyl group
${({C H}_{3})}_{3}$ N is less basic due to steric hindrance by bulky methyl group prevent any acid to take a lone pair of nitrogen.

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