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Question

Suitable reagents (s) to convert acetyl chloride into acetaldehyde is/are :
(a). Na−C2H5OH
(b). NaBH4
(c). H2/pd−BaSO4
(d). LiAIH(CHe3)3

A
a,b,c
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B
c,d
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C
b,c,d
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D
a,b,c,d
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Solution

The correct option is C c,d
To convert acid chloride to its corresponding acetaldehude, Rosenmund reduction reaction is used.
Catalyst used is H2PαBaSO4 which is poisoned using Quinoline or Sulphur.reaction that takes place is as follows :-


1052883_996126_ans_b75cd3b93f03428a99375e7c3d314ad2.png

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