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Question

Sulphur forms the chlorides S2Cl2 and SCl2. The equivalent mass of sulphur in SCl2 is 16g/ mol. Therefore, the equivalent mass of sulphur in S2Cl2 is:

A
32g/ mol
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B
16g/ mol
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C
64g/ mol
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D
8g/ mol
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Solution

The correct option is B 32g/ mol
Equivalent mass of sulphur can be calculated by the equation:
Equivalent mass=molar mass of elementvalency of the element in the compound

Therefore, the equivalent mass of sulphur in SCl2 is calculated as follows (taking the valency as +2):
Equivalent mass of sulphur=322=16g/mol

Similarly, in the case of S2Cl2 (taking the valency as +2),
Equivalent mass of sulphur=32×22=32g/mol

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