Question

Sulphur is pharamagnetic in nature at its vapour state I miss question

Answer 1

Sulfur exist as S8 molecule at ordinary temperature and pressure but at elevated temperature it gets dissociated and partly exists as S₂ molecule in vapor phase
In vapour state, Sulphur partly exists as S₂ molecule, which has two unpaired electrons in antibinding pie orbitals, just like the O₂ molecule. Hence, it exhibits paramagnetism.