The correct option is D Hydrogen sulphide
Sulphuric acid reacts with sodium sulphide to give sodium sulphate and hydrogen sulphide (H2S) gas.
Na2S(s)+H2SO4(aq)→Na2SO4(aq)+H2S(g)
H2S gas is colourless, highly flammable and has a characterisitc rotten egg smell. When inhaled in large quantities, hydrogen sulphide causes headache to humans.