The correct option is D primary calcium phosphate and gypsum
Superphosphate is defined as most important phosphorus fertilizer, derived by action of sulfuric acid on phosphate rock (mostly tribasic calcium phosphate) to produce a mix of gypsum and monobasic calcium phosphate. A mixture of gypsum and monobasic calcium phosphate resulting from the action of sulfuric acid on phosphate rock, used as a fertilizer.