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Question

Suppose that after both valves are opened, the entire apparatus is cooled to lower the final internal pressure to 1.0 atm. What is the contribution of N2 gas to this final pressure?

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A
0.40 atm
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B
0.35 atm
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C
0.30 atm
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D
0.25 atm
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Solution

The correct option is A 0.25 atm
Since the temperature is same, the number of moles will be directly proportional to PV
nN2nHe=PN2VN2PHeVHe=4.1×6.00.82×10=13
The mole fraction of nitrogen will be 11+3=0.25
The partial pressure of nitrogen will be 0.25×1=0.25atm

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