Suppose the potential energy between an electron and a proton at a distance r is given by −ke2/3r3. Use Bohr's theory to obtain energy level of such a hypothetical atom.
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Solution
Given, potential energy, U=−ke23r3
The electrostatic force between electron and proton at a distance r is given by, F=dUdr=ke2r4
According to Bohr's first postulate, mv2r=F=ke2r4...(1)
According to Bohr's second postulate, mvr=nh2π........(2)
From (1) and (2), r=4π2e2kmn2h2
Total energy of the electron, E=K+U=12mv2−ke23r3=ke22r3−ke23r3=ke26r3 using (1)
Substituting the value of r, we get E=n6h66(2π)6m3k2e4