Chlorophyll a is essential for photosynthesis because only its special molecules function as reaction centres (P700,P660). Reaction centres convert light energy into chemical or electron energy. Photosynthesis is, therefore, absent in plants lacking chlorophyll a.The importance of chlorophyll b and other accessory pigments is
(i) Absorption of light rays of different wavelengths and transfer of this enery to reaction centre through resonance, (ii) Protection of chlorophyll a reaction centre from nascent oxygen and other destructive radicals.