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Question

Suppose we carry out the reaction of Iodine on ethylene in presence of UV light such that the obtained product is symmetrical. Which of the following options are accurate?

A
The oxidation state of Iodine increases.
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B
The oxidation state of Carbon increases.
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C
Both (A) and (B)
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D
None of these
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Solution

The correct option is B The oxidation state of Carbon increases.
Ethylene undergoes reduction with iodine to form 1,2-Diiodoethane
CH2=CH2+I2ICH2CH2I
(Ethylene) (Iodine) (1,2-Diiodoethane)

Now that we have figured the product, check the validity of each of the given options. Clearly Iodine is more electronegative than Carbon. So the electrons in the CI bond will be closer to the Iodine atom. Hence, Iodine will be assigned a -1 oxidation state. Overall, the molecule is neutral. In ethylene, each Carbon atom has -2 oxidation state while in 1,2-Diiodoethane, each Carbon has -1 oxidation state.

The oxidation state of Carbon increases.

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