The correct option is D 33
P(X=r) will be maximum when r is the mode. There are two cases for mode of binomial distribution:
Case 1: If (n+1)/p is an integer the Binomial distribution is bi modal and the two modal values are (n+1)/p and (n+1)/p - 1.
Case 2: If (n+1)/p is not an integer there exists unique modal value and it's the integral part of (n+1)/p.
The Given Binomial distribution has parameters, n= 100 and p= 1/3.
We have (n+1)/p = 101/3 = 33.67, which is not an integer.
Hence the unique mode is 33, the integral part of (n+1)/p.