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Question

Temperature at which most probable speed of O2 becomes equal to root mean square speed of N2 is:[Given:N2 at 427C]

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Solution

Root mean square speed is vr=3RTM
For N2,M=14×2=28
vr=3RT28=3×8.314×(427+273)28=
Most probable speed is vr=2RTM
For O2,M=16×2=32
vM=2RTM=2×8.314×T32
Now,
3×8.314×(427+273)28=2×8.314×T32
T=1200K

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