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Nucleophilic Substitution in Alkyl Halides

tert-alkyl ha...

Question

tert-alkyl halides are practically inert to substitution by SN2 mechanism because of:

A

Insolubility

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B

Instability

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C

Inductive effect

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D

Steric hindrance

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Solution

The correct option is D
Steric hindrance

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Similar questions

tert-alkyl halides are practically inert to substitution by SN2 mechanism because of:

Q. Tertiary alkyl halides are practically inert to substitution by

S_{N} 2

mechanism because?

Q. Tertiary alkyl halides are practically inert to sutstitution by

S_{N} 2

mechanism because:

Q. Tertiary alkyl halides are particularly not substituted by

S_{N} 2

mechanism, because of:

Q. Alkyl halides and alcohols easily undergo nucleophilic substitution either through

S_{N} 1

S_{N} 2

mechanism. The relative case of these two processes depends upon the nature of the substrate (alkyl group) as well as leaving group, nature of nucleophile and also upon the nature of the solvent.

S_{N} 1

mechanism involves the formation of carbocation as intermediate while

S_{N} 2

mechanism involves the formation of a transition pentavalent state.

S_{N} 1

is the main mechanism in

3^{0}

alkyl halides and alcohols, while

S_{N} 2

mechanism is the path adopted by most of the

1^{o}

2^{o}

alkyl halides may follow

S_{N} 1

S_{N} 2

.

What happens when

1^{o} R O H

H X

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Nucleophilic Substitution in Alkyl Halides

Standard XIII Chemistry

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