Th amount of energy needed to form the radicals CH3,1o,2o and 3o decreases in the order
We know that the stability of radicals in the following order due to the +I effect of the alkyl group(s) in more branched radicals:3o>2o>1o>CH3.
Since the energy of an unstable species is more and the energy of a stable species is less, the methyl radical will be at the highest energy level and so on. Hence , the energy required to form the least stable methyl radical is the greatest and so on.
so b is the answer