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Question

Th amount of energy needed to form the radicals CH3,1o,2o and 3o decreases in the order

A
3o>2o>1o>CH3
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B
CH3>1o>2o>3o
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C
1o>2o>3o>CH3
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D
CH3>3o>2o>1o
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Solution

The correct option is B CH3>1o>2o>3o

We know that the stability of radicals in the following order due to the +I effect of the alkyl group(s) in more branched radicals:3o>2o>1o>CH3.

Since the energy of an unstable species is more and the energy of a stable species is less, the methyl radical will be at the highest energy level and so on. Hence , the energy required to form the least stable methyl radical is the greatest and so on.

so b is the answer


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