Th e energy required to break one mol of Cl-Cl bonds in Cl2 is 242 kJmol-1. The longest wavelength of light capable of breaking a single Cl-Cl bond is
A. 594nm
B.640nm
C. 700nm
D.494nm
494nm
Explanation:Cl2→2Cl⋅
ΔH=+242xkJ/mol
I will work out the energy required to dissociate 1 molecule of Cl2:
E=242×1036.022×1023=4.0186×10−19xJ
Now I use the Planck Expression:
E=hf=hcλ
∴λ=hcE
λ=6.63×10−34×3×1084.0186×10−19xm
λ=4.94×10−7xm
λ=494nm
hope this helps :)