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Question

Thallium shows different oxidation states because -


A

It is a transition metal

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B

Of inert pair effect

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C

Of its amphoteric character

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D

Of its high reactivity

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Solution

The correct option is B

Of inert pair effect


Inert pair effect is the phenomenon in which outer shell (ns2)electrons penetrate to
(n - 1) d electrons and thus becomes closer to nucleus and are more effectively pulled towards nucleus. This results in less availability of ns electrons for bonding. The inert pair effects begins when n = 4 and increases with increasing value of n.


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