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Question

The acid which does not form an anhydride when treated with P2O5 is:

A
Formic acid
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B
Acetic acid
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C
Propionic acid
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D
Benzoic acid
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Solution

The correct option is A Formic acid
Phosphorus pentoxide is a dehydrating agent.
It abstracts a molecule of water from formic acid to form carbon dioxide.
HCOOHP2O5−−CO2+H2O.
Thus, formic acid which does not form an anhydride when treated with P2O5.

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