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Question

The acidic, aqueous solution of ferrous ion forms a brown complex in the presence of NO3 by the following two steps. Complete and balance the equations:

[Fe(H2O)6]2++NO3+H+(a)+Fe(H2O)6]3++H2O

[Fe(H2O)6]2++(b)(c)+H2O

The product c is [Fe(H2O)5NO]2+

If the given statement is true enter 1, else enter 0.

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Solution

The acidic, aqueous solution of ferrous ion forms a brown complex in the presence of NO3 by the following two steps.
6[Fe(H2O)6]2++2NO3+6H+(2NO)+6Fe(H2O)6]3++4H2O
[Fe(H2O)6]2++(NO)([Fe(H2O)5NO]2+)+H2O

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