The acidic character in acetic acid is due to the presence of replaceable
H
Acetic acid is a carboxylic acid and the acidic character in carboxylic acid is due to the presence of the replaceable hydrogen atom in the carboxylic group.
CH3−O||C−OHH2O−−→CH3−O||C−O−+H+
When we dissolve acetic acid in water, H+ ions are generated which is responsible for its acidic character.