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Question

The addition of 0.15 moles of Na2SO4 to an aqueous solution containing 0.05 moles of BaCl2 results in the formation of an insoluble white precipitate of BaSO4. Find the limiting reagent and the amount ofBaSO4 that gets formed.


A
Na2SO4, 11.65 g
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B
BaCl2, 34.95 g
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C
Na2SO4, 34.95 g
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D
BaCl2, 11.65 g
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Solution

The correct option is D BaCl2, 11.65 g
Na2SO4+BaCl22NaCl+BaSO4
Moles of Na2SO4 = 0.15 moles
Moles of BaCl2 = 0.05 moles
1 mole of Na2SO4 reacts with 1 mole of BaCl2
0.15 moles of Na2SO4 will react with 0.15 moles of BaCl2
So, BaCl2 is the limiting reagent.
As per the reaction, 1 mole of BaCl2 produces 1 mole of BaSO4
0.05 moles of BaCl2 will produce 0.05 moles of BaSO4
Amount of precipitate formed = moles of BaSO4 formed × Molar mass of BaSO4
Amount of precipitate formed = 0.05×233=11.65 g

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