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Byju's Answer
Standard IX
Chemistry
Arrehenius Theory of Acids and Bases
The addition ...
Question
The addition of pyridinium ion
C
5
H
5
N
H
+
on the position of the equilibrium. The
p
H
will be ?
A
Decrease
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B
Increase
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C
No change
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D
Can't say
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Solution
The correct option is
C
Decrease
As we add pyridinium ion at eqm, equilibrium shifts towards backside
C
5
H
5
N
+
[
H
+
]
=
→
C
5
H
5
N
H
+
The solution will have more no of hydrogen ion in solution so pH of solution decreases.
(
∵
p
H
=
−
l
o
g
[
H
+
]
)
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Similar questions
Q.
p
H
of the solution will be raised by addition of pyridinium ion
C
5
H
5
N
H
+
on the position of the equilibrium.
Q.
A
0.25
M
solution of pyridinium chloride
C
5
H
5
N
H
+
C
I
−
was found to have a pH of
2.75
. What is
K
b
for pyridine,
C
5
H
5
N
?
Q.
Equilibrium constant for the following reaction is
1
×
10
−
9
:
C
5
H
5
N
(
a
q
.
)
+
H
2
O
(
l
)
⇌
C
5
H
5
N
H
+
(
a
q
.
)
+
O
H
−
(
a
q
.
)
Determine the mole of pyridinium chloride
(
C
5
H
5
N
.
H
C
I
)
that should be added to 500 mL solution of 0.4 M pyridine
(
C
5
H
5
N
)
to obtain a buffer solution of pH = 5:
Q.
Assertion :On addition of
N
H
4
C
l
to
N
H
4
O
H
solution,
p
H
decreases but remains greater than
7
. Reason: Addition of
N
H
+
4
ion decreases ionisation of
N
H
4
O
H
thus
[
O
H
−
]
is decreased hence,
p
H
decreases.
Q.
For the following reaction, select the statement that best describes the change.
R
C
H
2
O
H
+
P
C
C
[
C
5
H
5
N
H
+
C
l
C
r
O
−
3
]
⟶
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