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Question

The air pollutant NO is produced in automobile engines from the high temperature reaction N2(g)+O2(g)2NO(g);Kc=1.7×103 at 2300K. If the initial concentrations of N2 and O2 at 2300K are both 1.40M, what are the concentrations of NO,N2, and O2 when the reaction mixture reaches equilibrium?

A
[NO]=0.056M,[N2]=[O2]=1.37M
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B
[NO]=0.045M,[N2]=0.23M,[O2]=1.37M
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C
[NO]=0.367M,[N2]=[O2]=2.03M
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D
[NO]=0.056M,[N2]=0.57M,[O2]=0.12M
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Solution

The correct option is A [NO]=0.056M,[N2]=[O2]=1.37M
N2(g)+O2(g)2NO(g)
1.4 1.4
at eqm 1.4-x 1.4-x 2x
Kc=(2x)2/(1.4x)2=17×104;2x/(1.4x)=4.12×102
2x=[NO]=0.056M
[N2]=[O2]=1.37.

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