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Question

The alcohol that gives a blue coloured solution after treating it with Red P and I2 followed by a reaction with AgNO2 and then, to the product formed, adding HNO2 and by treating the product with an alkali is:

A
1–hydroxybutane
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B
2–hydroxybutane
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C
2–hydroxy–2–methylpropane
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D
1-hydroxy-2-methylpropane
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Solution

The correct option is B 2–hydroxybutane
The given sequential process represents the Victor Mayer's test. It is a test to distinguish alcohols. Primary alcohols gives red colour, secondary alcohol gives blue colour and tertiary does not produce any colour.
In the given options, 2-hydroxybutane is a secondary alcohol and is the correct answer.

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