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Question

The alcohol that produces turbidity immediately with ZnCl2 and conc. HCl at room temperature is:

A
butanol
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B
butan-2-ol
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C
2-methylpropan-2-ol
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D
2-methylpropanol
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Solution

The correct option is A 2-methylpropan-2-ol
The Lucas reagent (HCl+ZnCl2) reacts most rapidly with tertiary alcohols due to its ability to form tertiary carbocation with ease and this is the reason that it produces turbidity immediately.
Therefore, 2-methylpropan-2-ol is the correct answer.

Option C is correct.

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