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Question

The alkyne which gives the above ketone as the only product after hydration with H2O,H2SO4 and HgSO4 is x-heptyne. What is x?

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Solution

On hydration of 1-heptyne first, the OH group and H are added across triple bond then rearrangement takes place to form the corresponding ketone.
Here we get Hept-2-one as a product.

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