The correct option is A 6.625 g
We know,
Molarity M=moles of solutevolume of solution (mL)×1000
So, moles of solute = Molarity M × volume of solution
Moles of solute = 0.25×2501000 = 0.0625 g
molar mass of Na2CO3 = 106 g/mol
mass of solute = 0.0625×106 = 6.625g