The amount of energy released when a million atoms of iodine are completely converted into I– ions in the vapour state according to the equation, I(g)+e–→I–(g) is 5.0×10–13 J. Calculate the electron gain enthalpy of iodine in terms of kJmol–1.
A
−150.5kJ/mol
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B
−301kJ/mol
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C
−602kJ/mol
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D
−30.1kJ/mol
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Solution
The correct option is B−301kJ/mol The electron gain enthalpy of iodine is equal to the energy released when 1 mole of iodine atoms in vapour state are converted into I–ions. = −5×10−13×6.023×1023106 =-30.1×104J = -301kJ