The angle between the tangent at a point on a circle and the radius at the point of contact is
90o
Take point Q outside the circle on the line XY which is a tangent to the circle with centre O at the point of contact P.
OQ > OP For every point on the line XY except the point P, OP is the shortest of all the distances of the point o to the points of XY.
So, OP is the perpendicular to XY. Or it makes an angle of 90o with the tangent XY.