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Question

The anion [NiCl4]2 is paramagnetic but when CN ions are added, the product [Ni(CN)4]2 is diamagnetic because in [NiCl4]2, Cl is a weak ligand and thus, electrons are unpaired in Ni2+ making it paramagnetic, sp3 hybridised and tetrahedral.
If true enter 1, else enter 0.

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Solution

[NiCl4]2(aq)+4CN(aq)[Ni(CN)4]2(aq)+4Cl(aq)
In [NiCl4]2Cl is a weak ligand. Thus, electrons are unpaired in Ni2+ making it paramagnetic. It is a high spin complex. It is sp3 hybridised and has tetrahedral structure.
When strong ligand like CN is added, substitution takes place and electrons are paired in [Ni(CN)4]2. It is a low spin complex. It is dsp2 hybridised and has square planar structure.
Hence, the given statement is true.

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