The apparent coefficient of expansion of a liquid when heated in a copper vessel is C and when heated in a silver vessel is S. If A is the linear coefficient of expansion of copper, then the linear coefficient of expansion of silver is -
When a liquid expands in a vessel, we measure a value of the expanded liquid less than the actual value, owing to the expansion of the vessel.
Let -
γr = coefficient of real expansion of the liquid;
γa = coefficient of apparent expansion of the liquid;
γv = coefficient of expansion of the vessel.
We can write,
γr = γa + γv.
For copper,γr = C + 3 αcu = C + 3A;
for silver,γr = S + 3 αAg.
Comparing,
C + 3A = S + 3 αAg
⇒ αAg = C−S+3A3.