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Question

The aqueous solution of 'A' is alkaline due to

A
the presence of Ca2+ ions
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B
the presence of H3BO3
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C
hydrolysis of B4O27
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D
hydrolysis of CO23
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Solution

The correct option is C hydrolysis of B4O27
A is borax or sodium tetraborate (Na2B4O7.10H2O).

One mole of A contains 10 moles of water of crystallization.

It is a white crystalline solid and is used in water softening. Its aqueous solution is alkaline due to the formation of sodium hydroxide upon hydrolysis of Na2B4O7. The reaction is as follows:

Na2B4O7+7H2O2NaOH+4H3BO3

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