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Question

The arrangement of (CH3)3C−,(CH3)2CH−,CH3CH2− when attached to benzene or an unsaturated group in increasing order of inductive effect is

A
(CH3)3C<(CH3)2CH<CH3CH2
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B
CH3CH2<(CH3)2CH<(CH3)3C
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C
(CH3)2CH<(CH3)4C<CH3CH2
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D
(CH3)3C<CH3CH2<(CH3)2CH
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Solution

The correct option is A (CH3)3C<(CH3)2CH<CH3CH2
In general greater the number of alkyl groups attached to a positively charged C-atoms, the greater is the hyperconjugation interaction and stabilization of the cation.
Hyperconjugation effect increases in the order,
(CH3)C<(CH3)2CH<CH3CH2.
Hence, ans is A.

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