Fluorine in its elemental state is a highly electronegative element in the periodic table. Fluorine atom has an electronic configuration of 1s2 2s2 2p5. So, it is one electron less to form a stable octate or to attain a noble gas configuration. So, Fluorine atom gains one electron to change to flouride anion (F−) to attain stable octate. This formation of fluoride releases energy so, formula of fluoride ion is exothermic.