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Question

The azide ion has:

A
20 outer electrons and is isoelectronic with Br2O
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B
18 outer electrons and is isoelectronic with NO2
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C
16 outer electrons and is isoelectronic with CO2
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D
14 outer electrons and is isoelectronic with H2O2
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Solution

The correct option is C 16 outer electrons and is isoelectronic with CO2
N3¯NN¯N
Azide ion has 16 outer electrons (5 valence electrons from each nitrogen atom +1 for negative charge).
Total number of electrons are 22 (7 from each nitrogen atom +1 for negative charge). Total number of electrons in CO2 are 22 (6 from carbon and 8 each from oxygen atom).

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