The balanced equation in basic medium is - S2O2-4 - Ag2O OH- Ag - SO32-

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The balanced ...

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The balanced equation in basic medium is :

$S_{2} O_{4}^{2 -} + A g_{2} O O H^{-} \to A g + S O_{3}^{2 -}$

S_{2} O_{4}^{2 -} + A g_{2} O + 2 O H^{-} \to 2 A g + 2 S O_{3}^{2 -} + H_{2} O

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S_{2} O_{4}^{2 -} + 2 A g_{2} O + 2 O H^{-} \to 2 A g + S O_{3}^{2 -} + H_{2} O

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2 S_{2} O_{4}^{2 -} + 3 A g_{2} O + 2 O H^{-} \to 2 A g + 2 S O_{3}^{2 -} + H_{2} O

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M n O_{4}^{-} (a q) + B r^{-} (a q) \to M n O_{2} (s) + B r O_{3}^{-} (a q)

M n O_{4}^{-} (a q) + B r^{-} (a q) \to M n O_{2} (s) + B r O_{3}^{-} (a q)

Z n (s) + A g_{2} O (s) + H_{2} O (l) ⇌ 2 A g (s) + Z n^{2 +} (a q) + 2 O H^{-} (a q)

Z n^{2 +} (a q) + 2 e^{-} \to Z n (s); E^{\circ} = - 0.76 V

A g_{2} O (s) + H_{2} O (l) + 2 e^{-} \to 2 A g (s) + 2 O H^{-} (a q), E^{\circ} = 0.34 V

Z n (s) + A g_{2} O (s) + H_{2} O (l) ⇌ 2 A g (s) + Z n^{2 +} (a q) + 2 O H^{-} (a q)

Z n^{2 +} (a q) + 2 e \to Z n (s); E^{0} = - 0.76 V

A g_{2} O (s) + H_{2} O (l) 2 e \to 2 A g (s) + 2 O H^{-} (a q), E^{0} = 0.34 V

Δ_{r} G^{o}

Z n_{(s)} + A g_{2} O_{(s)} + H_{2} O_{(l)} \to Z n_{(a q)}^{2 +} + 2 A g_{(s)} + 2 O H_{(a q)}^{-}

[E_{A g_{2} O / A g}^{o} = 0.344 V, E_{Z n^{2 +} / Z n}^{o} = - 0.76 V]

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