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Oxides and Oxoanions

The basic cha...

Question

The basic character of the transition metal monoxides follows the order:
(Atomic number Ti=22, V=23, Cr=24, Fe=26)

TiO > FeO > VO > CrO

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TiO > VO > CrO > FeO

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TiO > CrO > VO > FeO

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CrO > VO > FeO > TiO

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Solution

The correct option is B TiO > VO > CrO > FeO
Ionic transition metal oxides are basic and as we move along a row, covalent nature increases so basic character decreases.
TiO > VO > CrO > FeO

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F e O

2

V O

5.75

{F e}_{2} O_{3}

V O + {F e}_{2} O_{3} \to F e O + V_{2} O_{5}

V O_{4}^{3 -}, C r O_{4}^{2 -}, M n O_{4}^{2 -}, F e O_{4}^{2 -}

V O + F e_{2} O_{3} \to F e O + V_{2} O_{5}

V_{2} O_{5}

V_{2} O_{5}

5.75

F e_{2} O_{3}

V O + F e_{2} O_{3} \to F e O + V_{2} O_{5}

= 56

= 51

= 16

V O + F e_{2} O_{3} ⟶ F e O + V_{2} O_{5}

V_{2} O_{5}

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