The BCl3 is a planar molecule, whereas NCl3 is pyramidal because:
A
N−Cl bond is more covalent than B−Cl bond
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B
B−Cl bond is more polar than N−Cl bond
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C
Nitrogen atom is smaller than boron
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D
BCl3 has no lone pair but NCl3 has a lone pair of electron
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Solution
The correct option is BN−Cl bond is more covalent than B−Cl bond The BCl3 is a planar molecule, whereas NCl3 is pyramidal because BCl3 has no lone pair but NCl3 has a lone pair of electron Hence option D is correct.