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Question

The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is

A
Acidic permanganate
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B
Acidic dichromate
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C
Chromic anhydride in glacial acetic acid
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D
Pyridinium chloro-chromate
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Solution

The correct option is C Chromic anhydride in glacial acetic acid
Strong oxidising agents like acidified KMnO4 or K2Cr2O7 oxidised alcohols to carboxylic acids. For oxidation of primary alcohols to ketones, Pyridinium chloro-chromate(PCC) is used and for oxidation of secondary alcohols to ketones, Chromic anhydride in glacial acetic acid is used.

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