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Question

The boiling point of 0.2 mol kg1solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is true in this case ?


A

Y is undergoing dissociation in water while X undergoes no change.

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B

X is undergoing dissociation in water.

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C

Molecular mass of X is greater than the molecular mass of Y.

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D

Molecular mass of X is less than the molecular mass of Y.

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Solution

The correct option is B

X is undergoing dissociation in water.


Molality of solution of x = molality of solution of y = 0.2 mol/kg

By elevation in boiling point relation

ΔTb=iKbm or ΔTb i

ΔTb of solution of ‘x‘ > ΔTb of solution of ‘y‘.

’i' of solution of x >i of solution of ‘y‘ Solute of ‘x‘ undergoing dissociation.


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