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Question

The boiling point of a 0.1M solution of CaCl2 should be elevated by:

A
exactly 0.51
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B
somewhat less than 1.02
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C
exactly 1.02
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D
somewhat less than 1.53
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Solution

The correct option is D somewhat less than 1.53
For dilute solution, molarity is approximately equal to molality
The elevation in the boiling point ΔTb=i×Kb×m=3×0.52×0.1=0.156oC
Hence, the boiling point of a 0.1 M solution of CaCl2 should be elevated by 0.156oC

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