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Question

The boiling point of water at 735 torr is 99 C. The mass of NaCl added in 100 gm of water (Kb=0.51K kg mol3) to make its boiling point at 100C is:

A
10.68 g
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B
5.34 g
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C
2.67 g
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D
26.7 g
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Solution

The correct option is A 5.34 g
Give: Kb=0.51 K kg mol1
ΔTf=10099=1 K

Using the relation, ΔTf=Kf×m
m=10.51=1.96

n=0.5×1.96×100×103=0.098

mass=0.098×58.5=5.34 g

Hence, option B is the correct answer.

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