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Question

The bond angle is the lowest in which of the following species?

A
H3O+
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B
NH+4
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C
F2O
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D
BCl3
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Solution

The correct option is C F2O
In F2O, there are two lone pairs and two bond pairs of electrons. Due to the lone pair - lone pair repulsions and high electronegativity of F, the bond angle of FOF decreases and found to be less than 109.5o.
H3O+ has a tetrahedral geometry and is pyramidal in shape as it has one lone pair of electrons and the bond angle is around 107o.

NH+4 has a tetrahedral geometry with a bond angle of 109.5o.

BCl3 has a trigonal planar geometry with a bond angle of 120o.

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