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Question

The bond length order in following compound is:
731318_08ff7d6c033f4612862d76d53a4348d7.png

A
x>y>z>w
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B
z>y>x>w
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C
y>z>x>w
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D
z>x>y>w
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Solution

The correct option is A x>y>z>w
Since double bond has σ as well as n-bond so it is more stronger than σ bond (single bond).
Bond order = w>z>y>x
Bond length α1bondorder = w<z<y<x
i.e. exo bonds are lengthier than endo due to flexibility.

976879_731318_ans_c7b077440cd8453ca9ca1582b04c2a93.png

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