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Question

The Born Haber cycle below represents the energy changes occurring at 298K when KH is formed from its elements
v : ΔHatomisation K=90kJ/mol
w : ΔHionisation K=418kJ/mol
x : ΔHdissociation H=436kJ/mol
y : ΔHelectronaffinity H=78kJ/mol
z : ΔHlattice KH=710kJ/mol
On complete reaction with water, 0.1g of KH gave a solution requiring 25 cm3 of 0.1M HCl for neutralisation.Calculate the relative atomic mass of potassium from this information.

A
39
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B
40
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C
41
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D
None of these
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Solution

The correct option is A 39
Meq. of KH = Meq. of HCl
0.1EKH×1000=25×0.1
Valency factor (05955) of K is 1 hence
EK=MK MK=39
EKH=40 EKH=EK=
40=EK+1 EKH
EK 39

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