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Question

The Born-Haber cycle for formation of rubidium chloride (RbCl)is given below (the enthalpies are in kCal mol1).
Find the value of X.
830147_4c0e1695c98944dbb64e2e21c978fe19.png

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Solution

Heat of formotion = Heat of sublimation + Dessolution energy +Ionzation + energy + (electron affnutr+)
Substituting values
ΔHf=ΔHS+ΔHD+ΔIE+ΔEa+ΔU
105=+20.5+28.75+96.0+X159.5
X=90.75 Kcel/mol

1448841_830147_ans_2a11efdff9ce448ca5341903958c3f28.png

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