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Question

The CC bond length is 1.54 Ao, C=C bond length is 1.33 Ao. What is the circumference of benzene ring?

A
(3×1.54+3×1.33)Ao
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B
(4×1.54+21.33)Ao
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C
(6×1.4)Ao (1.4 is bond length between single and double bonds)
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D
(4×1.33+2×1.54)Ao
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Solution

The correct option is C (6×1.4)Ao (1.4 is bond length between single and double bonds)
In benzene due to resonance CC bond length is in between double bond and single bond.

i.e., (1.54+1.33)2=2.872=1.4 Ao.

Hence circumference is 6×CC bond length (1.4).

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