The capacity of a vessel is 3 litre. It contains 6 gm oxygen, 8 gm nitrogen and 5 gm CO2 mixture at 27∘C. If R = 8.31 J/mole ×´ kelvin, then the pressure in the vessel in N/m2 will be (approx.)
A
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B
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C
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D
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Solution
The correct option is A
Dalton’s law P=P1+P2+P3=μ1RTV+μ2RTV+μ3RTV=RTV[μ1+μ2+μ3]=RTV[m1M1+m2M2+m3M3] =8.31×3003×10−3[632+828+544]=498×103≅500×103≅5×105N/m2