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Question

The carbonate of a metal is isomorphous with MgCO3 and contains 6.091% of carbon. Atomic weight of the metal is nearly:

A
48
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B
68.5
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C
137
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D
120
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Solution

The correct option is C 137

The molecular formula of metal carbonate is MCO3 as it is isomorphous with MgCO3.

Let the mass of metal be M. Molecular weight of this carbonate =(M+12+48). Mass percentage of carbon in this compound =6.091

6.091100×(M+12+48)=12

M=12×1006.09160

M=137


Atomic wt. of the element is 137.01 amu which is Barium and the metal carbonate is BaCO3


Hence, the correct option is C


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