The correct option is A Al(C2H5)3+TiCl4
Ziegler Natta catalyst (R3Al+TiCl4) is generally used in the polymerisation of 1-alkenes (ethylene and alkenes with the vinyl double bond).
Heterogeneous supported catalysts based on titanium compounds are used in the polymerization reactions in combination with co-catalysts, i.e., organoaluminium compounds such as triethylaluminium, Al(C2H5)3.